Universitat Jaume I - UJI - Castello

Investigacions Analítiques

Publicacions recents 2007/2012

Estrategias analíticas para el control de contaminantes orgánicos prioritarios en aguas de lixiviado de plantas de tratamiento de RSU.
E. Pitarch, F. López, J. Marin, F. Albarrán, F. Hernández.
Analítica de los Residuos, 95:46-55 (2007)

Quantification and confirmation of priority organic micropollutants in water by LC-tandem mass spectrometry.
E. Pitarch, J.M. Marin, F. López, E. Hogendoorn, F. Hernández.
Intern. J. Environ. Anal. Chem, 87(4):237-248(2007)

Liquid chromatography/tandem mass spectrometry determination of (4S,2RS)-2,5,5-trimethylthiazolidine-4-carboxylic acid, a stable adduct formed between D-(-)penicillamine and acetaldehyde (main biological metabolite of ethanol), in plasma, liver and brain rat tissues.
E. Serrano, O. Pozo, J. Beltrán, F. Hernández, L. Font, M. Miquel, C.M.G. Aragon.
Rapid Commun. Mass Spectrom., 21:1221-1229 (2007)

Use of Liquid Chrmatography Coupled to Quadrupole Time-of-Flight Mass Spectrometry to Investigate Pesticide Residues in Fruits.
S. Grimalt, O.J. Pozo, J.V. Sancho, F. Hernández.
Anal. Chem., 79:2833-2843 (2007)

Antibiotic residue determination in environmental waters by LC-MS. 
F. Hernández,  J.V. Sancho, M. Ibañez, C. Guerrero.
Trends in Anaytical Chemistry. 26(6):466-485 (2007)

Methodical approach for the use of GC-TOF MS for screening and confirmation of organic pollutants in environmental water.
T. Portolés, E. Pitarch, F. López, J.V. Sancho, F. Hernández.
Journal of Mass Spectrometry, 42: 1175-1185 (2007)

Secondary interactions, an unexpected problem emerged between hydroxyl containing analytes and fused silica capillaries in anion-exchange micro liquid chromatograph
A. Castillo, O.J. Pozo, A.F. Roig-Navarro
Journal of Chromatography A 1172:179-185 (2007)

Stable isotope determination in wild and farmed gilthead sea bream (Sparus aurata) tissues from the western Mediterranean
R. Serrano, M. A. Blanes, L. Orero
Chemosphere, 69: 1075-4080 (2007)

Biomagnification of organochlorine pollutants in farmed and wild gilthead sea bream (Sparus aurata) and stable isotope characterization of the trophic chains
R. Serrano, M. A. Blanes, F. J. López
Science of the Total Environment, 389: 340-349 (2008). Available online October 22^nd 2007

The even-electron rule in electrospray mass spectra of pesticides
E. M. Thurman, I. Ferrer, O. J. Pozo, J. V. Sancho, F. Hernández
Rapid Commun. Mass Spectrom. 21: 3855-3868 (2007)

Multiresidue pesticide analysis of fruits by ultra-performance liquid chromatography tandem mass spectrometry
O. J. Pozo, M. Barreda, J. V. Sancho, F. Hernández, J. Ll. Lliberia, M. A. Cortés, B. Bagó
Anal Bioanal Chem 389: 1765-1771 (2007)

Target and nontarget screening of organic micropollutants in water by solid-phase microextraction combined with gas chromatography/high-resolution time-of-flight mass spectrometry
F. Hernández, T. Portolés, E. Pitarch, F. J. López
Anal Chem 79: 9494-9504 (2007)

PM₁₀ speciation and determination of air quality target levels. A case study in a highly industrialized area of Spain.
M. C. Minguillón, X. Querol, A. Alastuey, E. Monfort, E. Mantilla, M. J. Sanz, F. Sanz, A. Roig, A. Renau, C. Felis, J. V. Miró, B. Artiñano.
Science of the Total Environment 372: 382-396 (2007)

Impact of the implementation of PM abatement technology on the ambient air levels of metals in a highly industrialised area.
X. Querol, M. C. Minguillón, A. Alastuey, E. Monfort, E. Mantilla, M. J. Sanz, F. Sanz, A. Roig, A. Renau, C. Felis, J. V. Miró, B. Artiñano.
Atmospheric Environment 41: 1026-1040 (2007)

Anodic dissolution of nickel across two consecutive electron transfers.
J. Gregori, J. J. García-Jareño, D. Giménez-Romero, A. Roig, F. Vicente.
Journal of the Electrochemical Society 154(7): C371-C377 (2007)

Maternal transfer of organochlorine compounds to oocytes in wild and farmed gilthead sea bream (Sparus aurata)
R. Serrano, M. A. Blanes, F. J. López
Chemosphere, 70: 561-566 (2008)

Investigating the presence of pesticide transformation products in water by using liquid chromatography-mass spectrometry with different mass analyzers
F. Hernández, M. Ibañez, O. J. Pozo, J. V. Sancho
J. Mass Spectrom. 43: 173-184 (2008)

Pesticide residues and transformation products in groundwater from a Spanish agricultural region on the Mediterranean coast.
F. Hernández, J. M. Marin, O. J. Pozo, M. Ibañez, J. V. Sancho, F. J. López, J. V. Sancho
International Journal of Environmental Analytical Chemistry 88(6): 409-424 (2008)

Determination of PBDEs in human breast adipose tissues by gas chromatography coupled with triple quadrupole mass spectrometry.
C. M. Medina, E. Pitarch, F. J. López, C. Vázquez, F. Hernández
Anal Bioanal Chem 390: 1343-1354 (2008)

Fast determination of toxic diethylene glycol in toothpaste by ultra-performance liquid chromatography-time of flight spectrometry.
F. Hernández, M. Ibañez, J. V. Sancho
Anal Bioanal Chem 391: 1021-1027 (2008)

Rapid non-target screening of organic pollutants in water by ultraperformance liquid chromatography coupled to time-of-flight mass spectrometry.
M. Ibañez, J. V. Sancho, D. McMillan, R. Rao, F. Hernández.
Trends in Analytical Chemistry, 27(5): 481-489 (2008)

Investigating the presence of organochlorine pesticides and polychlorinated biphenyls in wild and farmed gilthead sea bream (Sparus aurata) from the west Mediterranean sea.
R. Serrano, M. Barreda, M. A. Blanes.
Marine pollution Bulletin 56: 963-972 (2008)

Characterization of the salinisation processes in aquifers using boron isotopes; application to Southern-East Spain.
I. Morell, A. Pulido-Bosch, F. Sánchez-Martos, A. Vallejos, L. Daniele, L. Molina, J. M. Calaforra, A. F. Roig.
Water Air Soil Pollut 187: 65-80 (2008)

Seasonal trends and tissue distribution of organochlorine pollutants in wild and farmer gilthead sea bream (Sparus aurata) from the western Mediterranean sea and their relationship with the environmental and biological factors.
M. A. Blanes, R. Serrano, F.J. López.
Arch Environ Contam Toxicol (2008)

Capabilities of microore columns coupled to inductively coupled plasma mass spectrometry in speciation of arsenic and selenium.
A. Castillo, A.F. Roig, O.J. Pozo
Journal of Chromatography A 1202: 132-137 (2008)

Collision-induced dissociation of 3-keto anabolic steroids and related compounds after electrospray ionization. Considerations for structural elucidation.
O. J. Pozo, P. Van Eenoo, K. Deventer, S. Grimalt, J. V. Sancho, F. Hernández, F.T. Delbeke
Rapid Communications in Mass Spectrometry 22: 4009-4024 (2008)

Investigation of pesticide metabolites in food and water by LC-TOF-MS.
F. Hernández, J. V. Sancho, M. Ibáñez , S. Grimalt
Trends in Analytical Chemistry 27(10): 862-872 (2008)

Application of head-space solid-phase microextraction coupled to comprehensive two-dimensional gas chromatography–time-of-flight mass spectrometry for the determination of multiple pesticide residues in tea samples.
J. Schurek, T. Portolés, J. Hajslova, K. Riddellova , F. Hernández
Analytica Chimica Acta 611: 163-172 (2008)

Application of multiple headspace-solid-phase microextraction followed by gas chromatography-mass spectrometry to quantitative analysis of tomato aroma components.
E. Serrano, J. Beltrán, F. Hernández
Journal of Chromatography A 1216: 127-133 (2009)

Searching for anthropogenic contaminants in human breast adipose tissues using gas chromatography-time-of-flight mass spectrometry.
F. Hernández , T. Portolés, E. Pitarch, F. López
Journal of Mass Spectrometry 44: 1-11 (2009)

Application of ultra-high-pressure liquid chromatography-tandem mass spectrometry to the determination of multi-class pesticides in environmental and wastewater samples Study of matrix effects.
J.M. Marín, E. Gracia, J. V. Sancho, F. López, F. Hernández
Journal of Chromatography A 1216: 1410-1420 (2009)

Screening of antibiotics in surface and wastewater samples by ultra-high-pressure liquid chromatography coupled to hybrid quadrupole time-of-flight mass spectrometry.
M. Ibáñez, C. Guerrero, J.V. Sancho, F. Hernández
Journal of Chromatography A 1216: 2529-2539 (2009)

Simultaneous ultra-high-pressure liquid chromatography–tandem mass spectrometry determination of amphetamine and amphetamine-like stimulants,cocaine and its metabolites, and a cannabis metabolite in surface water and urban wastewater.
L. Bijlsma, J.V. Sancho, E. Pitarch, M. Ibáñez, F. Hernández
Journal of Chromatography A 1216: 3078-3089 (2009)

Determination of mycotoxins in different food commodities by ultra-high-pressure liquid chromatography coupled to triple quadrupole mass spectrometry.
E. Beltrán, M. Ibáñez, J.V. Sancho, F. Hernández
Rapid Communications in Mass Spectrometry 23: 1801-1809 (2009)

Determination of sub-ppb epichlorohydrin levels in water by on-line solid-phase extraction liquid chromatography/tandem mass spectrometry.
C. Ripollés, J. M. Marín, F.J. López, J.V. Sancho, F. Hernández
Rapid Communications in Mass Spectrometry 23: 1841-1848 (2009)

Combined Use of GC-TOF MS and UHPLC-(Q)TOF MS To Investigate the Presence of Nontarget Pollutants and Their Metabolites in a Case of Honeybee Poisoning.
T. Portolés, M. Ibáñez, J.V. Sancho, F.J. López, F. Hernández
Journal of Agricultural and Food Chemistry 57: 4079-4090 (2009)

A reliable analytical approach based on gas chromatography coupled to triple quadrupole and time-of-flight mass analyzers for the determination and confirmation of polycyclic aromatic hydrocarbons in complex matrices from aquaculture activities.
J. Nácher, R. Serrano, T. Portolés, F. Hernández, L. Benedito, J. Pérez
Rapid Communications in Mass Spectrometry 23: 2075-2086 (2009)

Use of ultra-high-pressure liquid chromatography–quadrupole time-of-flight MS to discover the presence of pesticide metabolites in food samples.
F. Hernández, S. Grimalt, O. J. Pozo, J. V. Sancho
J. Sep. Sci. 32: 2245-2261 (2009)

GC-MS/MS multi-residue method for the determination of organochlorine pesticides, polychlorinated biphenyls and polybrominated diphenyl ethers in human breast tissues.
C.Medina, E. Pitarch, T. Portolés, F.J. López, F. Hernández
J. Sep. Sci. 32: 2090-2102 (2009)

Effects of fish oil replacement and re-feeding on the bioaccumulation of organochlorine compounds in gilthead sea bream (Sparus aurata L.) of market size.
J. Nácher , R. Serrano, L. Benedito, J.C. Navarro, F.J. López , J. Pérez
Chemosphere 76: 811-817 (2009)

Seasonal trends and tissue distribution of organochlorine pollutants in wild and farmed gilthead sea bream (Sparus aurata) from the Western Mediterranean sea and their relationship with environmental and biological factors.
M.A. Blanes, R. Serrano, F.J. López
Arch. Environ. Contam. Toxicol.57: 133-144 (2009)

Assessment of the health and antioxidant trade-off in gilthead sea bream (Sparus aurata L.) fed alternative diets with low levels of contaminants.
A. Saera, L. Benedito, A. Sitjá, J. Nácher, R. Serrano, S. Kaushik, J. Pérez
Aquaculture 296: 87-95 (2009)

Detection and structural investigation of metabolites of stanozolol in human urine by liquid chromatography tandem mass spectrometry.
O. Pozo, P.v. Eenoo, K. Deventer, L. Lootens, S. Grimalt, J.V. Sancho, F. Hernández, P. Meuleman, G. Leroux-Roels, F.T. Delbeke
Steroids 74: 837-852 (2009)

Detection and Characterization of a New Metabolite of 17α-Methyltestosterone.
Oscar J. Pozo, Peter Van Eenoo, Koen Deventer, Leen Lootens, Wim Van Thuyne, Maria K. Parr, Wilhelm Schänzer, Juan V. Sancho, Felix Hernández, Philip Meuleman, Geert Leroux-Roels, Frans T. Delbeke.
Drug Metabolism and disposition 37(11): 2153-2162 (2009)

Determination of melamine in milk-based products and other food and beverage products by ion-pair liquid chromatography–tandem mass spectrometry
María Ibáñez, Juan V. Sancho, Félix Hernández
Analytica Chimica Acta 649: 91-97 (2009)

Bioaccumulation markers and biochemical responses in European sea bass (Dicentrarchus labrax) raised under different environmental conditions
Luna Greco, Roque Serrano, Miguel A. Blanes, Elena Serrano, Ettore Capri.
Ecotoxicology and Environmental Safety 73: 38-45 (2010)

Bioaccumulation of Polycyclic Aromatic Hydrocarbons in Gilthead Sea Bream (Sparus aurata L.) Exposed to Long Term Feeding Trials with Different Experimental Diets.
J. Nacher, R. Serrano, L. Benedito, J. C. Navarro, F. J. López, S. Kaushik , J. Perez.
Archives of Environmental Contamination Toxicology 59: 137-146 (2010)

Multiple Spiking Species-Specific Isotope Dilution Analysis by Molecular Mass Spectrometry: Simultaneous Determination of Inorganic Mercury and Methylmercury in Fish Tissues.
A. Castillo, P. Rodríguez, G. Centineo, A.F. Roig, J. I. García .
Analytical Chemistry, 82: 2773-2783 (2010)

Multi-residue determination of 130 multiclass pesticides in fruits and vegetables by gas chromatography coupled to triple quadrupole tandem mass spectrometry.
M. I. Cervera, C. Medina, T. Portolés, E. Pitarch, J. Beltrán, E. Serrahima, L. Pineda, G. Muñoz, F. Centrich, F. Hernández
Analytical and Bioanalytical Chemistry, 397: 2873-2891 (2010)

Analytical strategy based on the use of liquid chromatography and gas chromatography with triple-quadrupole and time-of-flight MS analyzers for investigating organic contaminants in wastewater.
E. Pitarch, T. Portolés, J. M. Marín, M. Ibáñez, F. Albarrán, F. Hernández
Analytical and Bioanalytical Chemistry, 397: 2763-2776 (2010)

Simultaneous determination of triazines and their main transformation products in surface and urban wastewater by ultra-high-pressure liquid chromatography–tandem mass spectrometry
F. Benvenuto, J. M. Marín, J. V. Sancho, S. Canobbio , V. Mezzanotte, F. Hernández
Analytical and Bioanalytical Chemistry, 397: 2791-2805 (2010)

Mass Spectrometry: Fourth conference of the Spanish Society of Mass Spectrometry (SEEM)
F. Hernández, J. V. Sancho, D. Barceló
Analytical and Bioanalytical Chemistry, 397: 2761-2762 (2010)

Potential of atmospheric pressure chemical ionization source in GC-QTOF MS for pesticide residue analysis.
T. Portolés, J.V. Sancho, F. Hernández, A. Newton, P. Hancock
Journal of Mass Spectrometry, 45: 926-936 (2010)

Simultaneous determination of acidic, neutral and basic pharmaceuticals in urban wastewater by ultra high-pressure liquid chromatography-tandem mass spectrometry.
Emma Gracia-Lor, Juan V. Sancho, Félix Hernández
Journal of Chromatography A, 1217: 622-632 (2010)

Building an empirical mass spectra library for screening of organic pollutants by ultra-high-pressure liquid chromatography/hybrid quadrupole time-of-flight mass spectrometry.
Ramón Díaz, María Ibáñez, J.V. Sancho, F. Hernández
Rapid Communications in Mass Spectrometry, 25: 355-369 (2011)

UHPLC­MS/MS highly sensitive determination of aflatoxins, the aflatoxin metabolite M1 and ochratoxin A in baby food and milk.
Eduardo Beltrán, María Ibáñez, Juan Vicente Sancho, Miguel Ángel Cortés, Vicent Yusà,Félix Hernández
Food Chemistry, 126: 737-744 (2011)

Rapid wide-scope screening of drugs of abuse, prescription drugs with potential for abuse and their metabolites in influent and effluent urban wastewater by ultrahigh pressure liquid chromatography­quadrupole-time-of-flight-mass spectrometry.
Félix Hernández, Lubertus Bijlsma, Juan V. Sancho, Ramon Díaz, María Ibáñez
Analytica Chimica Acta, 684: 96-106 (2011)

Development and validation of a rapid and wide-scope qualitative screening method for detection and identification of organic pollutants in natural water and wastewater by gas chromatography time-of-flight mass spectrometry.
Tania Portolés, Elena Pitarch, Francisco J. López, Félix Hernández
Journal of Chromatography A, 1218: 303-315 (2011)

Gas chromatography coupled to high-resolution time-of-flight mass spectrometry to analyze trace-level organic compounds in the environment, food safety and toxicology
Félix Hernández, Tania Portolés, Elena Pitarch, Francisco J. López
Trends in Analytical Chemistry, 30 (2): 388-400 (2011)

Comparison between triple quadrupole, time of flight and hybrid quadrupole time of flight analysers coupled to liquid chromatography for the detection of anabolic steroids in doping control analysis
Oscar J. Pozo, Peter Van Eenoo, Koen Deventer, Hisham Elbardissy, Susana Grimalt, Juan V. Sancho, Felix Hernandez, Rosa Ventura, Frans T. Delbeke
Analytica Chimica Acta, 684: 107-120 (2011)

Multi-class determination of around 50 pharmaceuticals, including 26 antibiotics, in environmental and wastewater samples by ultra-high performance liquid chromatography–tandem mass spectrometry
Emma Gracia-Lor, Juan V. Sancho, Félix Hernández
Journal of Chromatography A, 1218: 2264-2275 (2011)

Investigación de los productos de transformación del herbicida bromacilo en aguas sometidas a procesos de cloración
F. Javier García Castillo, Carlos Ferrer Torregrosa, Belén Sánchez-Rubio , María Ibáñez Martínez, Félix Hernández, Juan V. Sancho Llopis
Tecnologia del agua 329: 2-7 (2011)

Use of soft and hard ionization techniques for elucidation of unknown compounds by gas chromatography/time-of-flight mass spectrometry
Tania Portolés, Elena Pitarch, Francisco J. López, Félix Hernández, Wilfried M. A. Niessen
Rapid Communications in Mass Spectrometry 25: 1589-1599 (2011)

Investigation of organophosphate esters in fresh water, salt and brine samples by GC-TOF MS
Jaime Nácher Mestre, Roque Serrano, Tania Portolés, Félix Hernández
Analytical Methods, 3: 1779-1785 (2011)

Fragmentation pathways of drugs of abuse and their metabolites based on QTOF MS/MS and MSE accurate-mass spectra
Lubertus Bijlsma, Juan V. Sancho, Félix Hernández, Wilfried M. A. Niessen
Journal of Mass Spectrometry, 46: 865-875 (2011)

Determination of volatile organic compounds in water by head space-solid-phase microextraction gas chromatography coupled to tandem mass spectrometry with triple quadrupole analyzer
M.I. Cervera, J. Beltran, F.J. Lopez, F. Hernandez
Analytica Chimica Acta, 704: 87-97 (2011)

Non-target screening of organic contaminants in marine salts by gas chromatography coupled to high-resolution time-of-flight mass spectrometry
Roque Serrano, Jaime Nácher-Mestre, Tania Portolés, Francisco Amat, Félix Hernández
Talanta, 85: 877-884 (2011)

Mass spectrometric characterization of urinary toremifene metabolites for doping control analyses
C. Gómez, O.J. Pozo, R. Diaz, J.V. Sancho, E. Vilaroca, J.P. Salvador, M.P. Marco, F. Hernandez, J. Segura, R. Ventura
Journal of Chromatography A, 1218: 4727-4737 (2011)

Determination of eight nitrosamines in water at the ng L−1 levels by liquid chromatography coupled to atmospheric pressure chemical ionization tandem mass spectrometry
Cristina Ripollés, Elena Pitarch, Juan V. Sancho, Francisco J. López, Félix Hernández
Analytica Chimica Acta, 702: 62-71 (2011)

Is NMR-based metabolomic analysis of exhaled breath condensate accurate?
J.L. Izquierdo Garcia, G. Peces-Barba, S. Heili, R. Diaz, E. Want , J. Ruiz-Cabello
European Respiratory Journal, 37: 468-470 (2011)

Long-term postharvest aroma evolution of tomatoes with the alcobaça (alc) mutation
Joan Casals, Jaime Cebolla-Cornejo , Salvador Roselló, Joaquim Beltrán, Francesc Casañas, Fernando Nuez
European Food Research and Technology, 233: 331-342 (2011)

Evaluation of Genotype and Environment Effects on Taste and Aroma Flavor Components of Spanish Fresh Tomato Varieties
Jaime Cebolla-Cornejo, Salvador Roselló, Mercedes Valcarcel, Elena Serrano, Joaquim Beltrán, Fernando Nuez
Journal of Agricultural and Food Chemistry, 59: 2440-2450 (2011)

Determination of per- and polyfluorinated substances in airborne particulate matter by microwave-assisted extraction and liquid chromatography-tandem mass spectrometry
Maria Isabel Besera, Olga Pardo, Joaquim Beltrán, Vicent Yusà
Journal of Chromatography A, 1218: 4847-4855 (2011)

Use of quadrupole time-of-flight mass spectrometry to determine proposed structures of transformation products of the herbicide bromacil after water chlorination.
María Ibáñez , Juan V. Sancho, Oscar J. Pozo, Félix Hernández
Rapid Communications in  Mass Spectrometry, 25: 3103-3113 (2011)

Analytical study on ethephon residue determination in water by ion-pairing liquid chromatography/tandem mass spectrometry.
Cristina Ripollés, José M. Marín, Juan V. Sancho, Francisco J. López, Félix Hernández
International Journal of Environmental Analytical Chemistry, 91 nº14: 1380-1391 (2011)

Retrospective LC-QTOF-MS analysis searching for pharmaceutical metabolites in urban wastewater.
Felix Hernández, María Ibáñez, Emma Gracia, Juan V. Sancho
Journal of Separation Science, 34: 3517-3526 (2011)

Target and non-target screening strategies for organic contaminants, residues and illicit substances in food, environmental and human biological samples by UHPLC-QTOF-MS.
Ramón Díaz, María Ibáñez, Juan V. Sancho, Félix Hernández
Analytical Methods, 4: 196-209 (2012)

Rapid screening of arsenic species in urine from exposed human by inductively coupled plasma mass spectrometry with germanium as internal standard.
Angel Castillo, Clara Boix, Neus Fabregat, Antoni F. Roig, J.A. Rodriguez
Journal of Analytical Atomic Spectrometry, 27: 354-358 (2012)